A novel spray-based technique enables the production of high quality, free, uncoated semiconductor nanocrystals. Their collection, following spray droplet desolvation during flight, could result in unusual structures. We report on spray-produced ordered clusters (~50nm diameter) of MnS nanocrystals with grain size range of l-2nm, and their assembly into micron-sized coral-shaped fractal aggregates. Ballistic cluster-particle aggregation, with the introduction of physical interaction between particles, is suggested as a model for the assemblies' growth.
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