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Palladium Hydrogenation Catalysts Prepared Using Porous Carbon Materials Derived from Poly(Vinyl Chloride)

机译:使用衍生自聚(氯乙烯)的多孔碳材料制备的钯氢化催化剂

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摘要

The applicability of porous carbon materials obtained by the dehydrochlorination of poly(vinyl chloride) as supports for palladium hydrogenation catalysts was demonstrated. The efficiency of the catalysts was evaluated in the liquid-phase hydrogenations of styrene, nitrobenzene, chlorobenzene, and acetophenone. The complete conversion of the substrates with selective formation of target products was achieved under mild reaction conditions and at low Pd content in the catalysts (1.5 wt%).
机译:通过聚(氯乙烯)的脱氯化碳化作为钯氢化催化剂的载体所获得的多孔碳材料的适用性。在苯乙烯,硝基苯,氯苯和苯乙酮的液相氢化中评价催化剂的效率。在温和的反应条件下,在轻度反应条件下和催化剂中的低PD含量(1.5wt%)实现基材的完全转化。

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