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Study of atrazine adsorption kinetics by using an activated carbon synthesised from water hyacinth

机译:用水凝集合成的活性炭研究阿特拉嗪吸附动力学研究

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In this work, atrazine, one of the most widely used herbicides in Thailand, was removed from water by activated carbon synthesized from water hyacinth. Before adsorption, 3 types of activated carbons used as adsorbents were prepared by different chemical treatment methods; untreated activated carbon (AC), HCl-treated activated carbon (HCl-AC) and NaOH-treated activated carbon (NaOH-AC). After pyrolysis, NaOH-AC became ash, so it was not suitable for using as an adsorbent. Brunauer-Emmett-Teller (BET) and CHNS methods were used to characterised 2 other adsorbents and the results showed that HCl treatment could improve the surface area and carbon content. This led to the better performance of HCl-AC for removing atrazine from water comparing to AC confirming by the adsorption experiments. In addition, the adsorption kinetics of HCl-AC, the best adsorbent in this research, was investigated by fitting with 4 kinetics models. The results showed that pseudo-second-order was the best kinetics model describing that the atrazine adsorption of HCl-AC was limited by adsorption and 2 active sites of adsorbent were required for adsorbing 1 molecule of atrazine.
机译:在这项工作中,阿特拉津是泰国最广泛使用的除草剂之一,由水葫芦合成的活性炭从水中除去水。在吸附之前,通过不同的化学处理方法制备3种类型的活性炭作为吸附剂;未处理的活性炭(AC),HCL处理的活性炭(HCl-AC)和NaOH处理的活性炭(NaOH-AC)。热解后,NaOH-AC成为灰,所以它不适合用作吸附剂。 Brunauer-Emmett-Teller(Bet)和CHNS方法用于表征2个其他吸附剂,结果表明,HCl治疗可以改善表面积和碳含量。这导致HCl-AC的性能更好地从水中除去阿特拉嗪与吸附实验的AC确认。此外,通过用4个动力学模型来研究HCl-AC的吸附动力学,HCl-AC是该研究中最佳吸附剂。结果表明,伪二阶是最佳动力学模型,其描述了HCl-Ac的吸附受吸附和吸附剂的2个活性位点,用于吸附1分子的亚唑嗪。

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