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Effect of lignin on the thermal properties of nanocrystalline prepared from kenaf core

机译:木质素对烯汞核心纳米晶体热性能的影响

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Lignin and cellulose work together to provide a structural function in plants.While cellulose is the primary load-bearing element,lignin acts as the matrix that provides stiffness and rigidity to the fibre.In the production of nanocellulose,the removal of lignin is essential which is done through bleaching.Nevertheless,studies have shown that lignin can impart positive effects on thermal stability besides being a natural compatibilizer due to the presence of both aliphatic and polar groups in the chain network.The objective of this study is to evaluate the effect of lignin on the thermal properties of nanocrystalline cellulose prepared from kenaf core.Nanocellulose of different lignin content was prepared by undergoing first,pulping using 20 % NaOH and 0.1 % anthraquinone(AQ)followed by a bleaching sequence.The study shows that,sample having the least amount of lignin had good thermal stability during the first and second stage of decomposition by shifting the temperature higher as compared to sample with higher lignin content.However,when the temperature reached more than 300 °C up to the end of the degradation process,the latter gave a higher amount of residue suggesting that lignin can help the NCC to withstand heat better.
机译:木质素和纤维素一起在植物中提供结构功能。纤维素是初级承载元件,木质素作为基质,作为为纤维提供刚度和刚性的基质。在纳米纤维素的生产中,木质素的去除是必不可少的通过漂白完成。从而表明,由于链网络中的脂族和极性基团存在,木质素除了存在外自然相容剂之外,木质素可以赋予热稳定性的积极影响。本研究的目的是评估效果通过首先进行,使用20%NaOH和0.1%蒽醌(AQ)进行不同木质素含量的纳米晶核的纳米晶纤维素的热性质。通过漂白序列,使用20%NaOH和0.1%蒽醌(AQ)制备不同木质素含量的纳米纤维素。研究表明,具有的样品在分解的第一和第二阶段,最小量的木质素通过将温度升高为COM的温度和第二阶段具有良好的热稳定性然而,用更高的木质素含量进行样品。然而,当温度达到300°C到降解过程的末端时,后者达到了更高量的残留物,表明木质素可以帮助NCC能够耐热地承受热量。

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