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Preparation of activated carbon from waste plastics polyethylene terephthalate as adsorbent in natural gas storage

机译:从废塑料聚乙烯对苯二甲酸乙二醇苷的活性炭制备天然气储存中的吸附剂

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The main problem is the process of natural gas storage and distribution, because in normal conditions of natural gas in the gas phase causes the storage capacity be small and efficient to use. The technology is commonly used Compressed Natural Gas (CNG) and Liquefied Natural Gas (LNG). The weakness of this technology safety level is low because the requirement for high-pressure CNG (250 bar) and LNG requires a low temperature (-161°C). It takes innovation in the storage of natural gas using the technology ANG (Adsorbed Natural Gas) with activated carbon as an adsorbent, causing natural gas can be stored in a low pressure of about 34.5. In this research, preparation of activated carbon using waste plastic polyethylene terephthalate (PET). PET plastic waste is a good raw material for making activated carbon because of its availability and the price is a lot cheaper. Besides plastic PET has the appropriate characteristics as activated carbon raw material required for the storage of natural gas because the material is hard and has a high carbon content of about 62.5% wt. The process of making activated carbon done is carbonized at a temperature of 400 ° C and physical activation using CO2 gas at a temperature of 975 ° C. The parameters varied in the activation process is the flow rate of carbon dioxide and activation time. The results obtained in the carbonization process yield of 21.47%, while the yield on the activation process by 62%. At the optimum process conditions, the CO2 flow rate of 200 ml/min and the activation time of 240 minutes, the value % burn off amounted to 86.69% and a surface area of 1591.72 m~2/g.
机译:主要问题是天然气储存和分配的过程,因为在天然气的天然气的正常条件下导致储存能力较小,有效地使用。该技术常用压缩天然气(CNG)和液化天然气(LNG)。这种技术安全水平的弱点是低,因为高压CNG(250巴)和LNG的要求需要低温(-161°C)。使用作为吸附剂的活性炭的技术Ang(吸附天然气)储存天然气储存的创新,使天然气可储存在约34.5的低压下。在本研究中,使用废塑料聚对苯二甲酸乙二醇酯(PET)制备活性炭。宠物塑料废物是一种良好的原料,用于制作活性炭,因为其可用性,价格更便宜。除塑料PET外,由于材料很硬,并且具有约62.5%的高碳含量,因此塑料PET具有适当的碳原料所需的活性炭原料。在975℃的温度下,在400℃的温度下,在400℃的温度下碳化制备活性炭的方法,并在975℃的温度下使用CO 2气体。在激活过程中变化的参数是二氧化碳和活化时间的流速。在碳化过程中获得的结果为21.47%,而活化过程的产率为62%。在最佳过程条件下,CO 2流速为200mL / min,活化时间为240分钟,值%烧掉量为86.69%,表面积为1591.72m〜2 / g。

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