Improvement of thermal and mechanical properties of composite based on polylactic acid and microfibrillated cellulose through chemical modification

摘要

Polylactic acid (PLA) is the most representative sustainable and bio-based polymer environmentally friendly that has a great potential to replace petroleum-based plastics. However, brittleness, low heat resistance, and slow crystallization limit the wide application of PLA. One of strategies to improve PLA properties is by reinforcing with microfibrillated cellulose (MFC). Unfortunately, the hydrophilic properties of MFC make it difficult to attain good dispersion in a hydrophobic PLA matrix. Therefore, modification of MFC was needed to increase its compatibility with PLA in the composite formation. In this experiment, MFC was modified with partial acetylation (degree of substitution: 1) and further grafted with lactide monomers through ring-opening polymerization using Sn(0ct)2 catalyst. The result of acetylation and grafting were verified by infrared spectra. Composites were prepared by mixing PLA (molecular weight of 200,000) and the modified MFC at 9:1 ratio through organic solvent method. Followed by 8 min-kneading and hot pressing at 180°C, the resulted composites were evaluated for their mechanical and thermal properties. Thermal characterization carried out using differential scanning calorimetry measurements showed that the presence of modified MFC increased the temperature of glass transition and accelerated the crystallization of PLA. Mechanical properties measurement showed that the presence of modified MFC enhanced the elongation at break (1.1 to 1.8%), tensile strength (14.9 to 25.7 MPa), and modulus of elasticity (1.7 to 2.1 GPa). These results demonstrated that the modified MFC could extend the application of PLA in industry.