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Hot tensile behaviour in silicon-killed boron microalloyed steels

机译:硅片硼微合金钢中的热拉伸行为

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Low carbon steel for drawing and cold heading applications should have low strength, high ductility and low strain ageing rates. To achieve this, nitrogen must be removed from solid solution, which can be done by low additions of boron. A wire producer had been experiencing occasional problems with severe cracking on silicon-killed, boron steel billets during continuous casting, but the solution was not obvious. Samples from four billets, each from different casts, were removed for analysis and testing. The tested steel compositions were within the specification limits, with boron to nitrogen ratios of 0.40-1.19. Hot ductility testing was performed on a Gleeble 1500 using parameters approximating the capabilities of this particular billet caster. The steel specimens were subjected to in situ melting, then cooled at a rate of 2 C.s~(-1) to temperatures in the range 750-1250°C, where they were then pulled to failure at a strain rate of 8×10~(-4) s~(-1). In this work, it was found that both the boron to nitrogen ratio and the manganese to sulphur ratio influenced the hot ductility and hence the crack susceptibility. Excellent hot ductility was found for B:N ratios above 1.0, which confirmed that the B:N ratio should be above a stoichiometric value of 0.8 to remove all nitrogen from solid solution. TEM analysis showed that coarse BN precipitates nucleated on other precipitates, such as (Fe,Mn)S, which have relatively low melting points, and are detrimental to hot ductility. Low Mn:S ratios of 10 - 12 were shown to promote precipitation of FeS, so a Mn:S > 14 was recommended. A narrower billet surface temperature range for straightening was recommended to prevent transverse surface cracking. Additionally, analysis of industrial casting data showed that the scrap percentage due to transverse cracking increased significantly for Mn:S < 14. An exponential decay relationship between the manganese to sulphur ratio and the average scrap percentage due to transverse cracking was derived as a simple tool to predict, and hence mitigate, scrap levels in the casting plant.
机译:用于绘图和冷镦应用的低碳钢应具有低强度,高延展性和低应变老化率。为此,必须从固溶体中除去氮,这可以通过低加入硼来完成。在连续铸造期间,电线生产商一直在偶尔在硅杀死的硼钢坯上进行严重开裂的问题,但溶液不明显。除去来自四个坯料,每个来自不同铸件的坯料,用于分析和测试。测试的钢结构在规格限值范围内,硼至氮比为0.40-1.19。使用近似该特定贷款机脚轮的能力的参数对GLEEBLE 1500进行热延展性测试。对钢样品进行原位熔化,然后以2cs〜(-1)的速率冷却至750-1250℃的温度,然后以8×10的应变速率拉动它们失效。 (-4)S〜(-1)。在这项工作中,发现硼与氮率和含硫比的氮气影响,影响了热延展性并因此影响了裂缝敏感性。发现优异的热延展性对于高于1.0的B:n比,这证实了B:N比应高于0.8的化学计量值,以除去来自固溶体的所有氮。 TEM分析表明,在其他沉淀物上核化的粗BN沉淀,例如具有相对低熔点的(Fe,Mn)S,并且对热延展性有害。低Mn:10-12的S比率促进FES的沉淀,因此建议使用MN:S> 14。建议使用较窄的坯料表面温度范围,以防止横向表面裂缝。另外,工业铸造数据的分析表明,Mn:S <14的横裂引起的废料百分比显着增加。锰对硫比和横裂引起的平均废料百分比的指数衰减关系是一个简单的工具预测,因此减轻了铸造工厂的废气水平。

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