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BIOLEACHING OF REE FROM BAUXITES

机译:从铝土矿的芦荟生物浸出

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Alternative and sustainable sources of rare earth elements (REE) are critical to sustain a green energy future. Approximately 300 million tonnes of bauxite are processed annually primarily to extract alumina, but can contain moderate concentrations of REE, offering a potential alternative resource. The REE in bauxites are associated with a range of mineral phases, including iron oxy-hydroxides, fluorocarbonates (bastnaesite) and phosphates (xenotime). These minerals have been bioleaching targets in other deposits, through microbially-mediated organic acid production or redox reactions. Sequential extractions of Turkish bauxites show that between 4 and 17% total REE are acid soluble (acetic acid) and a further 17 to 42% are reducible (hydroxylammonium chloride) and 2 to 24% are oxidisable (hydrogen peroxide). To target the acid soluble fraction, we used Aspergillus sp. to produce organic acids. To target the reducible and oxidisable fractions we used Acidithiobacillus ferrooxidans grown on either sulphur or ferrous iron.
机译:稀土元素(REE)的替代和可持续的来源对于维持绿色能源未来至关重要。每年约有3亿吨铝土矿主要用于提取氧化铝,但可以含有适度浓度的REE,提供潜在的替代资源。铝土矿中的REE与一系列矿物相有关,包括铁氧 - 氢氧化铁,氟碳酯(BAstnaesite)和磷酸盐(Xenotime)。这些矿物通过微生物介导的有机酸产生或氧化还原反应是在其他沉积物中的生物浸出靶标。土耳其铝土矿的顺序提取表明,在4至17%的总重量之间是酸可溶(乙酸),另外的17至42%是可降解(氯化氢),2至24%是氧化(过氧化氢)。为了靶向酸可溶性级分,我们使用aspergillus sp。生产有机酸。为了靶向可降低和可氧化的级分,我们使用亚酸脱氧苷在硫或亚铁铁上生长。

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