Hydrogen Diffusion and Trapping in Fluoride Salt Melts and Graphite Electrodes

摘要

This paper presents an approach currently under development at University of Wisconsin Madison to study tritium transport in high temperature fluoride salt systems and absorption in graphite. This work has applicability to tritium management in Fluoride Salt Cooled High Temperature Nuclear Reactors (FHRs). The applicability of the Double Potential Step Method (DSPM) and Electrochemical Impendence Spectroscopy (EIS) originally developed for the study of hydrogen transport in metals from water solutions is discussed for the salt-graphite system. Mechanistic models for hydrogen transport and trapping in graphite are reviewed. The experimental setup and electrochemical cell used with 2LiF-BeF_2 (flibe) salt at 500-700°C is described. The design and preliminary characterization data for a Ni/Ni(II) flibe thermodynamic reference electrode are presented.