The interaction of different materials with the niobium containing melt was investigated. As substrate materials the ceramics, beryllium and carbopyroceram were chosen. Several spherical ceramic and beryllium samples were coated with protective molybdenum film by magnetron sputtering. After the experiment (exposition time 10 min) the exfoliation of molybdenum film from ceramic samples was observed due to interaction of the substrate with the melt. The beryllium samples regardless of the shape and the presence of the protective films were dissolved in the niobium containing melt due to more negative electrode potential comparing with niobium one. The carbopyroceram samples were exposed in the melt during 3 and 12 hours. It was found that the carbopyroceram it not corrodes in the niobium containing melt. The optimal regimes for electrodeposition of smooth uniform niobium coatings with the thickness up to 50 μm on carbopyroceram spheres were found.
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