The Role of Aluminium Source (Al_2O_3/AIN) in the Synthesis of the Ca-α-SiAION: Eu~(2+) Phosphor

摘要

The purpose of this paper was to compare the effect of changing the aluminium source in the mixture of initial powders on the properties of the final phosphor powder of Ca-a- SiAlON doped with Eu~(2+). The phosphor composition was designed as Eu_(0.048)Ca_(0.752)Si_(9.6)Al_(2.4)O_(0.8)Ni_(15.2) and it was prepared by the solid state reaction in a temperature range of 1450-1650°C. A1N and/or η-Al_2O_3 powders were used as a source of aluminium. It has been found that presence of aluminium nitride or oxide in the mixture of initial materials significantly changed the course of α-sialon formation, chemical composition of that solid solution and the resultant photoluminescence properties. It has been established that a small amount of η-Al_2O_3 with a suitable carbon addition was profitable for liquid formation and enhanced crystallization of Ca,Eu-α-sialon. The excessive oxide-rich liquid at reaction temperature led to sintering of phosphor particles and decreased emission intensity while lack of sufficient amount of liquid (nitrogen-rich starting composition) resulted in A1N presence and considerably reduced emission intensity of this phosphor.