Influence of CeO_2-Doping on the Electrical Properties of ZnO-Bi_2O_3-Based Varistor Ceramics

摘要

The microstructure and electrical properties of CeO_2-doped ZnO-Bi_2O_3-based varistors were investigated for different amounts of the dopant. The phase composition of CeO_2-doped samples was similar to the undoped samples. Ce mainly segregated at the grain boundaries within the EDS detection limit. The average grain size decreased from 7.3 to 6.7 μm and the breakdown voltage increased from 438 to 501 V/mm when the content of CeO_2 ranged from 0 to 0.2 mol%. The nonlinear coefficient increased from 38 to 51 when the content of CeO_2 increased from 0 to 0.1 mol%., but the further doping caused it to decrease up to 44 at 0.2mol%. The leakage current decreased from 1 to 0.4 uA/cm2 when the content of CeO_2 ranged from 0 to 0.1 mol%. Then it increased to 0.7 μA/cm~2 at 0.2 mol%. The density of interface states, the barrier height and the donor concentration increased when the content of CeO_2 ranged from 0 to 0.1 mol%, but decreased at 0.2 mol%. Hence, when the content ranges from 0 to 0.1 mol%, CeO_2 acts as a donor and can improve the electrical properties.