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The influence of metakaolin substitution by slag in alkali-activated inorganic binders for civil engineering

机译:矿渣矿泉素替代在土木工程中碱活化无机粘合剂的影响

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In this study the effect of metakaolin replacement by milled blast furnace slag in alkali-activated geopolymeric binder was investigated in accordance to their rheological and mechanical properties. It was demonstrated that slag addition into the metakaolin binder can improve mechanical properties of final products. Our investigation was focused oh broad interval of metakaolin substitution in the range from 100 to 40 volume per cents of metakaolin so that the volume content of solids in final binder was maintained constant. Prepared binders were activated by alkaline solution of potassium silicate with silicate module of 1.61. The particle size analyses were performed for determination of particle size distribution. The rheological properties were determined in accordance to flow properties by measurements on Ford viscosity cup and by oscillatory measurements of hardening process. For the investigation of hardening process, the strain controlled small amplitude oscillatory rheometry was used in plane-plate geometry. For determination of applied mechanical properties were binders filled by ceramic grog in the granularity range 0-1 mm. The filling was maintained constant at 275 volume per cents in accordance to ratio of solids in dry binder. The mechanical properties were investigated after 1, 7 and 28 days and microstructure was documented by scanning electron microscopy. The results indicate that slag addition have beneficial effect not only on mechanical properties of hardened binder but also on flow properties of fresh geopolymer paste and subsequent hardening kinetics of alkali-activated binders.
机译:在本研究中,根据流变和力学性能研究了碾磨的高炉渣中的Metakaolin替代矿物炉渣的影响。证明炉渣加入甲胶蛋白粘合剂可以改善最终产品的机械性能。我们的研究将OH广泛间隔的偏动素取代范围为100至40体积的甲状腺素,使得最终粘合剂中固体的体积含量保持恒定。通过硅酸钾的碱性溶液活化制备的粘合剂,硅酸钾模块为1.61。进行粒度分析以确定粒度分布。根据福特粘度杯的测量和通过硬化过程的振荡测量测量,根据流动性能测定流变性质。对于硬化过程的研究,在平面板几何形状中使用应变控制的小幅度振荡计流变。用于测定所施加的机械性质是粒度粒度填充的粘合剂,粒度范围为0-1mm。根据干粘合剂中固体的比例,将填料在每美分的275体积下保持恒定。在1,7和28天后研究了机械性能,通过扫描电子显微镜记录了微观结构。结果表明,不仅具有硬化粘合剂的机械性能,还具有有益的效果,而且还具有碱性地质聚合物浆料的流动性和随后的碱活化粘合剂的硬化动力学。

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