Ti–pillared interlayered clays have been synthesized by the exchange reaction between acid modified Tagan montmorillonite in Na-form with an aqueous solutions of TiCl_4 and characterized by XRD, N_2–adsorption/desorption analyses, temperature-programmed desorption of ammonia (TPD NH_3), transmission electron microscopy (TEM). The maximum conversion of n–hexane equal to 64.1 % was found on 0.35 %Pt/Ti (5,0) NaHMM + M-catalyst thus the yield of isohexanes makes 45.0 %. At the decrease of platinum amount to 0.1 %, the conversion of n-hexane decreases slightly it makes 61.7 %, and the yield of isohexanes increases by 1.4 %. According to TEM separate dense particles mainly with a sizes of 50– 100 ? are shown. Morelarger particles have the sizes within 200 ?. These particles can be related to the mixture of the phases Pt, PtTi, Pt_3Ti, TiO, TiO_2 that testify about strong interaction of the supported metal Pt with the support with formation of intermetallids (PtTi, Pt_3Ti) and oxides.
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