The synthesis of copper complex with 1D chain

摘要

The complex {[Cu(C_9H_8O_4)(DMSO)_2(H2O)_2]·(DMSO)_2}n (C_9H_8O_4= 2-Methyl-1,4-benzenedicarboxylic acid, DMSO = dimethyl sulfoxide) was synthesized by reaction of Cu(NO_3)_2 · 3H_2O. The crystal structure of the copper(II) complex has been determined and studied by X-ray diffraction. The complex is monoclinic, space group P2(1)/c, with a= 10.196 (3) A, b= 11.364(2) A, c= 16.921 (4) A, a=90.1, β=101.54, γ = 89.6°, V= 1960.59(6) A~3, Z= 4. The copper complex is 1D hydrophobic chain structure, because of the hydrophobic properties of the -CH_3.