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Comprehensive Spectral and Thermal Characterization of Oil Shales

机译:石油综合光谱和热表征油

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The heterogeneous nature of oil shale resources associated to the depositional environments,lithology, and organic content make the reserve estimation complex and unpredictable.However,comprehensive laboratory studies on organic rich shale samples collected from different regions can increase the understanding about the organic content of oil shales,interaction of shale with organic matter and injected fluid used during enhanced oil recovery method.This study investigates the characterization of eight different Turkish and American oil shale samples with several spectral methods and a thermal analysis. The main purpose of this study is to characterize the oil shale samples to increase the understanding about the organic content and interaction of shale with organic matter. In this study,we used Thermal Gravimetric Analysis/Differential Scanning Calorimetry(TGA/DSC) analysis to estimate organic content of each oil shale sample in air and nitrogen environments.X-Ray Diffraction(XRD)was used to define minerals in oil shale.Fourier Transform Infrared Spectroscopy (FTIR)was used to detect the mineral and kerogen in oil shale before and after the TGA/DSC analysis. Scanning Electron Microscope(SEM)was used to characterize the depositional environment of each oil shale samples.TGA/DSC results verified that oil shale samples have up to 50%of organic matter.XRD and FTIR results helped to identify the organic and inorganic compounds.Effects of minerals and ions were recognized by comparing TGA/DSC curves and FTIR spectra.It was recognized that the more carbonate ion in the oil shale the more increase in weight loss occurred.Diatoms identified from SEM results showed that depositional environments of the some oil shale samples are marine environments. This study provides insight for the reserve estimation of the eight different oil shale samples with comprehensive spectral and thermal characterization.
机译:与沉积环境,岩性和有机含量相关的石油页岩资源的异质性质使得储备估计复杂和不可预测。但是,从不同地区收集的有机丰富的页岩样品的综合实验室研究可以增加对油的有机含量的理解Shales,页岩与有机物质的相互作用和增强的采油方法中使用的注射液。本研究调查了八种不同土耳其和美国油页面样品的特征,具有几种光谱方法和热分析。本研究的主要目的是表征油页面样本,以增加对有机物有机物的有机含量和相互作用的理解。在这项研究中,我们使用热重分析/差示扫描量热法(TGA / DSC)分析来估计在空气和氮气environments.X射线衍射(XRD)的每个油页岩样品的有机成分被用来定义在油页岩矿物质。傅里叶变换红外光谱(FTIR)用于在TGA / DSC分析之前和之后检测油页岩中的矿物质和角质原。扫描电子显微镜(SEM)用于表征每个油页面样品的沉积环境.TGA / DSC结果证实,油页面样品高达50%的有机物质.XRD和FTIR结果有助于鉴定有机和无机化合物。通过比较TGA / DSC曲线和FTIR光谱来识别矿物质和离子的影响。识别出油页岩中的碳酸盐离子越多,来自SEM结果鉴定的体重减轻越多显示出一些油的沉积环境页岩样品是海洋环境。本研究为八种不同油页面样本的储备估计提供了综合光谱和热表征的洞察力。

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