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Durability of air entrained cement mortars under combined sulphate and freeze-thaw attack

机译:耐硫酸盐和冻融攻击下的空气夹带水泥砂浆的耐久性

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The paper deals with experimental results of combined sulphate expansion and freeze-thaw attack on air entrained (AE) and non-air entrained (nAE) ordinary portland cement mortars. After prior freezing and thawing of the 4x4x16 cm mortar bars the part of them was subjected to sulphate attack of the 5% Na2SO4 solution. Another part of mortar bars was immersed in the sulphate solution for 110 days and then these bars were frozen and thawed. The resistance of nAE and AE mortars to regular sulphate and freeze-thaw attacks alone was tested as well. In order to compare damage degree of mortars in all environments, there were investigated long term linear strains (expansion), and compressive strength of mortars. Also the SEM and XRD analyses of mortars were carried out. Compared to the individual sulphate attack alone, prior freeze-thaw and following it sulphate attack affected significant acceleration of sulphate expansion of nAE and AE mortars as well, despite much better resistance of AE mortars to freezing and thawing. However, the prior sulphate attack significantly reduced AE mortars resistance to freezing and thawing. The SEM analysis showed that air voids in AE mortars were partially filled with ettringite. Its precipitation in air voids of AE mortars caused that the volume of air was diminished and freeze-thaw resistance of AE mortars was significantly decreased and it was as low as resistance of nAE mortars was. The complete destruction of AE mortars subjected to sulphate attack alone occurred earlier than that of nAE mortars did. Based on SEM analysis results it is suggested that lower sulphate resistance of AE mortars was due to higher porosity of the air void-paste interface and its higher initial w/c ratio compared to 'bulk paste' farther away from.
机译:本文涉及硫酸盐膨胀和冻融攻击的实验结果,夹带(AE)和非空气夹带(NAE)普通波特兰水泥迫击炮。在冻结和解冻的4x4x16cm砂浆中后,将它们的一部分进行了5%Na 2 SO 4溶液的硫酸盐攻击。将砂浆棒的另一部分浸入硫酸盐溶液中110天,然后冷冻并解冻这些棒。还测试了NAE和AE砂浆对定期硫酸盐和冻融攻击的抵抗力。为了比较所有环境中的迫击炮度,研究了长期线性菌株(膨胀),以及迫击炮的抗压强度。还进行了迫击炮的SEM和XRD分析。与单独的单独硫酸盐攻击相比,先前的冻融和后硫酸盐侵袭也受到硫酸盐膨胀的显着加速,尽管AE砂浆对冻结和解冻的抗性有多抗抵抗力。然而,先前的硫酸盐攻击显着降低了AE迫击炮抗冻结和解冻的灰浆。 SEM分析显示AE砂浆中的空隙部分地填充了Ettringite。它在AE砂浆中的空隙中的沉淀使得空气量减少,AE砂浆的冻融抗性显着降低,并且与NAE砂浆的抗性一样低。单独发生硫酸盐攻击的AE迫击炮的完全破坏比NAE迫击炮迫使。基于SEM分析结果,建议较低硫酸盐的耐药性是由于空隙粘贴界面的孔隙率较高,而其较高的初始W / C比与“散装粘贴”更远的比率相比。

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