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CHEMISTRY OF MXenes: A NEW LARGE FAMILY OF 2D SOLIDS WITH EXCEPTIONAL PROMISE

机译:MxENes的化学:一个新的大家庭,2D固体,具有特殊的承诺

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By now it is well-established that the layered, hexagonal carbides and nitrides with the general formula, M_(n+1)AX_n, (MAX) where n = 1 to 3, M is an early transition metal, A is an A-group (mostly 13 and 14) element and X is either C and/or N combine some of the best attributes of metals and ceramics.fl] More recently, we have shown that by simply immersing MAX phase powders, at room temperature, in HF or HC1 and LiF solutions, the A-layers - mostly Al - are selectively etched to produce 2D materials that we labeled MXenes to emphasize the loss of the A-group element and their similarities to graphene (Fig. 1).
机译:到目前为止,众所周知,层状,六方碳化物和氮化物具有通式,M_(n + 1)Ax_n,(Max),其中n = 1至3,m是早期过渡金属,a是a-组(主要是13和14)元素和X是C和/或N组合金属和陶瓷的一些最佳属性。最近,我们已经表明,通过简单地将最大相粉末浸入室温,在HF中或HC1和LiF溶液,选择性地蚀刻A层,以产生2D材料,以产生标记的MXENE,以强调A组元素的损失及其与石墨烯的相似性(图1)。

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