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Development of Biogas Upgrading System with Membrane Separators

机译:膜分离器沼气升级系统的开发

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In Japan, biogas generated from sewage treatment plants are mostly utilized as auxiliary fuel for sewage sludge combustion and Combined Heat and Power (CHP) fuel, however, some excess biogas is usually just burned without energy recovery. Since Japanese major gas companies are legally required to utilize 80 % or more of excess biogas by 2015, they are expected to promote on-site and off-site utilizations of biogas. In general, biogas has a composition of around 60 vol % methane, 40 vol % carbon dioxide and trace impurities such as hydrogen sulfide, water vapor and siloxane. Even if these trace components are removed before fuel supply, available gas appliances are limited to boilers and CHPs with special specification because its calorific value is lower than city gas. In order to expand application of biogas, it is required to be upgraded to natural gas quality. Today, there are several types of technologies for biogas upgrading and the most popular technologies are pressurized water scrubbing, pressure swing adsorption (PSA), organic physical scrubbing and chemical scrubbing. In Japan, pressurized water scrubbing and PSA are adopted for biogas upgrading before gas grid injection. However pressurized water scrubbing is suitable for only large-scale plants and PSA method is low in methane recovery rate. Currently membrane separation technology has gained attention because of its high performance in methane separation from biogas and its compactness suitable for smaller scale plants. In addition, capital and operational costs of membrane separation system are expected lower than other systems although there are few cases of biogas upgrading with membrane technology in Japan. Since membrane separators are not developed for biogas upgrading in usual, there is not enough data of upgrading digestion gas from sewage treatment plants with membrane separators to estimate long-term performance and membrane replacement cycle. A long-term test of upgrading digestion gas with organic membrane separators was carried out on a pilot scale. Raw digestion gas generated from a sewage treatment plant in Yokohama city was provided for the test. Targeted values of the methane concentration and the recovery rate of the upgraded biogas were over 98 vol % and over 90 %, respectively.
机译:在日本,污水处理厂产生的沼气主要用于污水污泥燃烧和综合热量和功率(CHP)燃料的辅助燃料,但是,一些过量的沼气通常只是燃烧而没有能量回收。由于日本主要天然气公司在2015年通过80%或更多的过量沼气,预计将促进现场和沼气的现场使用。通常,沼气的组成约为60体积%的甲烷,40体积%的二氧化碳和痕量杂质,如硫化氢,水蒸气和硅氧烷。即使在燃料供应前除去这些痕量组件,可用的燃气电器仅限于具有特殊规格的锅炉和CHP,因为其热值低于城市气体。为了扩大沼气的应用,需要升级到天然气质量。今天,有几种类型的沼气升级技术,最受欢迎的技术是加压水擦洗,压力摆动(PSA),有机物理擦洗和化学擦洗。在日本,采用加压水擦洗和PSA在气体网格注射前升级。然而,仅加压水洗适用于大型植物,PSA方法低于甲烷回收率。目前膜分离技术由于其高性能在沼气中的高性能和适用于较小的尺寸植物的浓缩性而受到影响。此外,膜分离系统的资本和运营成本预计比其他系统低,尽管日本薄膜技术较少有沼气升级。由于通常不会为沼气升级而开发膜分离器,因此没有足够的数据通过膜分离器从污水处理厂升级消化气体以估计长期性能和膜更换循环。在先导秤上进行了用有机膜分离器提升消化气体的长期试验。为测试提供了从横滨市污水处理厂产生的原料消化气体。甲烷浓度的靶向值和升级的沼气的回收率分别超过98体积%和超过90%。

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