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Assessment of Potassium Chromate Inhibition and Adsorption on Type A513 Mild Steel in Simulated Contaminated Media

机译:模拟污染培养基中A513温和钢型铬酸钾抑制和吸附的评估

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The effect of potassium chromate (K2Cr04) compound on the inhibitive performance of type A513 mild steel was studied using linear and open circuit polarization technique with uAutolab PGstatlOl. The structural degradation tendency was observed with high resolution optical microscope. Data obtained from Tafel plot showed that the organic compound performed effectively in acid/chloride solution at all concentration of (K2Cr04) with average inhibitor efficiency above 60%. The outcome of the OCP showed a significant correlation with the LPR trend. The massive influence of the inhibitive compound on steel was seen as a chemisorption mechanism in which the corrosive anions and particulate were supressed significantly. The adsorption of the compound was determined and was found to obey the Langmuir isotherm model. The structural properties generally were affected with high aggressiveness of the acid/chloride ion mix with uniform corrosion propagation observed along the entire interface.
机译:使用Uautolab PGSTATLOL的线性和开路偏振技术研究了铬酸钾(K2CR04)化合物对A513温和钢抑制性能的影响。用高分辨率光学显微镜观察到结构降解趋势。从Tafel Plot获得的数据表明,在所有浓度(K2Cr04)的酸/氯溶液中有效地进行的有机化合物,其平均抑制剂效率高于60%。 OCP的结果显示出与LPR趋势的显着相关性。抑制化合物对钢的大规模影响被视为化学吸附机理,其中腐蚀性阴离子和颗粒显着压制。测定化合物的吸附,并发现术语遵守Langmuir等温线模型。结构性质通常受到酸/氯离子混合物的高侵蚀性,沿整个界面观察到均匀的腐蚀繁殖。

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