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Shock compression response of Ti+B reactive powder mixtures

机译:Ti + B反应性粉末混合物的冲击压缩响应

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The shock compression response of Ti+2B (1:2 Ti:B stoichiometric ratio) reactive powder mixtures at ~50% theoretical material density (TMD) is investigated for shock pressures up to 5 GPa to investigate the possible shock-induced chemical reactivity of this highly exothermic mixture. The shock adiabat is produced from instrumented parallel-plate gasgun impact experiments on encapsulated powders using poly-vinylidene fluoride (PVDF) stress gauges to measure the input and propagated stresses and wave speed in the powder. The shock compression regime is probed from crush-up to full density and onward to assess the potential onset of a shock-induced chemical reaction event in the powder mixture. A series of two-dimensional continuum meso-scale simulations on validated simulated microstructures are performed to predict the shock compression response and identify the meso-scale mechanics that are essential for reaction. The suitability of the synthetic microstructural representations is evaluated by comparing the experimental and predicted pressure traces.
机译:Ti + 2b(1:2 Ti:B化学计量比)的冲击压缩响应在〜50%理论物质密度(TMD)下进行反应性粉末混合物,用于休克压力,高达5GPa,以研究可能的冲击诱导的化学反应性这种高度放热的混合物。冲击绝热线从仪表平行板gasgun冲击实验中生产上使用聚偏二氟乙烯(PVDF)应力计测量输入和传播的应力,并在粉末波速封装粉末。探测冲击压缩制度从挤压到全密度和向内探测,以评估粉末混合物中的冲击诱导的化学反应事件的潜在发作。进行了一系列关于验证的模拟微结构的二维连续内的模拟模拟,以预测冲击压缩响应并识别对反应至关重要的中间规模力学。通过比较实验和预测的压力痕迹来评估合成微结构表示的适用性。

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