Photochemical Decomposition of Hydrogen Sulphide in the Gas Mixtures and Generation Molecular Hydrogen

摘要

The process of molecular hydrogen achievement during the photolysis of gas mixtures generated in the course of oil treatment processes and containing hydrogen sulfide has been studied in this work. The photochemical decomposition of hydrogen sulfide and the kinetics of hydrogen generation have been investigated in the wide range of temperature and hydrogen sulfide partial pressure variation. The role of "hot" hydrogen atoms and the mechanism of the on-going processes within the process of molecular hydrogen generation due to the photochemical decomposition of hydrogen sulfide have been discussed.