The improvement in physical property performance of first generation metallocene catalyzed linear low-density polyethylene (mLLDPE) over Ziegler-Natta (Z/N) LLDPE is counterbalanced by a decrease in processability: higher extruder pressures, more energy consumption and decreased bubble stability. NOVA Chemicals has developed a new class of single-site catalyzed LLDPE called SURPASS™ (sLLDPE) which overcomes the processability issues encountered with the traditional mLLDPE, while maintaining the enhanced physical property performance.rnThis paper focuses on:rn1. The effect of blow-up ratio, temperature profiles, film gauge and blend composition (LDPE/LLDPE) on blown film bubble instability and maximum output for sLLDPE .rn2. The comparison of bubble stability and maximum output of sLLDPE with conventional mLLDPE's resins.rn3. The application of analytical methods to predict resins' processability and bubble instability.
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机译:相较于齐格勒-纳塔(Z / N)LLDPE,第一代茂金属催化的线性低密度聚乙烯(mLLDPE)的物理性能的改善通过可加工性的降低得以抵消:更高的挤出机压力,更多的能耗和更低的气泡稳定性。 NOVA Chemicals开发了一种称为SURPASS™(sLLDPE)的新型单点催化LLDPE,它克服了传统mLLDPE遇到的可加工性问题,同时保持了增强的物理性能。吹胀比,温度曲线,薄膜规格和共混物组成(LDPE / LLDPE)对sLLDPE .rn2的吹塑薄膜气泡不稳定性和最大输出的影响。 sLLDPE与传统mLLDPE树脂的气泡稳定性和最大产量的比较。分析方法在预测树脂加工性和气泡不稳定性方面的应用。
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