Galvanostatic charge-discharge tests, ~(57)Fe and ~(119)Sn Moessbauer and XRD measurements on novel Sn-Ni-Fe electrodeposits

摘要

Novel Sn-Ni-Fe ternary alloys were successfully deposited by pulse plating technique from an electrolyte based on sodium gluconate which acts as a complexing agent. XRD results revealed the predominantly amorphous character for the majority of the deposits. ~(57)Fe and ~(119)Sn conversion electron Moessbauer spectroscopy indicated the formation of a paramagnetic amorphous alloy using a short on-pulse duration and where the Fe content was less than 22 wt.%. Galvanostatic charge-discharge tests of the novel Sn-Ni-Fe deposits were carried out in a model Li-ion cell and indicated that the Sn-Ni-Fe alloys have potential as an electrode material.