Rhodiun Complexes with Bident N-Heterocyclic Carbenes

摘要

Metal complexes of N-heterocyclic carbenes(NHCs)have attracted considerable attention in organometallic coordination chemistry,due to their successful application in homogeneous catalysis especially in C-C/C-N coupling reaction and olefin metatheses.Although a large number of transition-metal carbene complexes have been reported,investigations of rhodium complexes with bidentcarbeneligands have been limited so far[1-2].Herein we report our synthesis of rhodium complex with bident N-heterocyclic carbenes.