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Behavior to wear and corrosion of steel with chromium silicon nitride coatings

机译:用铬氮化硅涂料磨损钢的行为和腐蚀

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Chromium silicon nitride coatings were deposited via physical vapor deposition using a reactive sputtering magnetron, on steel specimens, with a chromium silicate target, purity of 99.5% and argon/nitrogen gas ratio (%) of 80/20. The coating characterization was carried out by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and nano hardness. The erosion-corrosion analysis was performed with a pin on disc tribometer, with a zircon pin, load of 1 N, applying three rotation speeds of the system (250 rpm, 400 rpm and 500 rpm) with an electrolyte composed of water, silica sand (0.05 mm, 0.1 mm and 0.15 mm) and 1% of sodium chloride. The electrochemical techniques used were resistance to polarization, electrochemical impedance spectroscopy and potentiodynamic polarization. The coating decreases the rate of substrate wear between 32% and 56%. The coefficient of friction decreases by almost 50% with the application of the film. Finally, the coating reduces by an order of magnitude the corrosion rate of steel in systems subject to wear and in 3 orders of magnitude in steel systems in static conditions, increasing the useful life of industrial facilities.
机译:铬氮化硅涂层通过物理气相沉积使用反应溅射磁控管,钢试样,硅酸铬靶标,纯度为99.5%,氩/氮气比(%)80/20。通过X射线衍射,扫描电子显微镜,能量分散X射线光谱和纳米硬度进行涂层表征。用磁盘摩特计的销进行腐蚀腐蚀分析,具有锆石销,1 n的负载,用电解质组成的电解质,硅砂,施加三个载荷,施加三个旋转速度(250 rpm,400 rpm和500 rpm) (0.05 mm,0.1 mm和0.15 mm)和1%的氯化钠。使用的电化学技术是抗极化,电化学阻抗光谱和电位偏振的抵抗力。涂层降低了衬底磨损率32%至56%。膜的摩擦系数随着薄膜的应用而降低近50%。最后,该涂层通过诸如在静态条件下磨损的系统中的钢的钢腐蚀速率和3个级别的钢结构中的3个数量级,增加了工业设施的使用寿命。

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