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Kinetics and Statistics of Vapor-Liquid-Solid Growth of III-V Nanowires

机译:III-V纳米线蒸气液固体生长的动力学和统计

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The use of semiconductor nanowires as new material building blocks for developing original devices is conditioned by the controllability of their growth. An important challenge is to form nanowires which include heterostructures of predictable dimensions. This objective requires a precise knowledge of the growth kinetics which appears much more complex for nanowires than for standard two-dimensional layers. Here, we present a method which provides detailed information on nanowire formation. The method is implemented with InP_(1-x)As_x nanowires grown by Au-catalyzed molecular beam epitaxy. Controlled and periodic modulations of the incident vapor phase are generated. Due to these modulations, the nanowires show small and short oscillations of composition along their growth axis. These oscillations furnish a time scale which is recorded in the nanowire solid phase. The instantaneous growth rate and the total length of individual nanowires at any time of the growth are accessible. Moreover, the distribution of the oscillation lengths contains the nucleation statistics. This statistics is shown to be strongly sub-Poissonian, which indicates that some regulation mechanism operates. The rapid depletion of group V atoms in the catalyst drop which follows the growth of each ML could explain the self-regulation of nucleation events.
机译:作为用于开发原始设备的新材料构建块的半导体纳米线的使用是通过其生长的可控性调节。重要挑战是形成纳米线,包括可预测尺寸的异质结构。该目标需要精确地了解生长动力学,这些动力学对于纳米线看起来比标准的二维层更复杂。在这里,我们提出了一种提供关于纳米线形成的详细信息的方法。该方法用Au催化分子束外延生长的INP_(1-x)AS_x纳米线实现。产生入射气相的控制和周期性调制。由于这些调制,纳米线沿着它们的生长轴显示了组合物的小而短的振荡。这些振荡提供在纳米线固相中记录的时间尺度。在任何时候瞬时生长速率和单个纳米线的总长度可获得。此外,振荡长度的分布包含成核统计。这一统计数据被证明是强烈的亚泊松,这表明一些规则机制运作。伴随每个mL生长的催化剂液滴中V原子的快速耗尽可以解释成核事件的自调节。

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