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Effect of Hydration-Dehydration Activation on the Basic Strength of Nano Structured Alkaline Earth Metal Calcium Oxide

机译:水化脱水活化对纳米结构碱土金属氧化钙基本强度的影响

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The study of physicochemical properties such as surface area, particle size and basicity of heterogeneous catalysts is in great interest nowadays. CaO yield a number of surface defects centers and these were important especially for heterogeneous catalyst. In this study, nano structured CaO was synthesized via hydration-dehydration method. The basic strength of the prepared CaO was also studied using simple back titration method with respect to the activation temperature. This result revealed that, the basic strength increases with the increasing of activation temperature. As the nano structured CaO were prepared, more surface cavity and defect were expected to be present and thus, exposing more O_2- sites, which influences the basic strength. Finally it was found that nano structured CaO was successfully prepared, while compared to the commercial CaO have a better chemical properties for catalytic chemical reactions.
机译:诸如异构催化剂的表面积,粒度和碱度等物理化学性质的研究是非常感兴趣的。 CaO产生许多表面缺陷中心,这些是对非均相催化剂的重要组合。在该研究中,通过水化脱水法合成纳米结构CaO。使用简单的后滴定法相对于活化温度,还研究了制备的CaO的基本强度。结果表明,基本强度随着激活温度的增加而增加。当制备纳米结构CaO时,预期更多的表面腔和缺陷存在,因此暴露更多O_2-位点,这影响了基本强度。最后发现,成功制备了纳米结构CaO,与商业CAO相比具有更好的化学性能,用于催化化学反应。

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