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Adsorption Kinetics of Lignite Activated Carbon in Treating Coal gasification Wastewater

机译:褐煤活性炭在处理煤气化废水中的吸附动力学

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Lignite activated carbon was provided through lignite which is treated specially. The adsorption capacity and mechanism of COD from Coal gasification wastewater by lignite activated carbon have been studied. The adsorption capacities of lignite activated carbon at different times were obtained by concentration of COD in the remainder solution. Three simplified kinetic models: pseudo-first-order, pseudo-second-order, intraparticle diffusion equations were adopted to examine the mechanism of the adsorption process. The results showed that the adsorption can be expressed by the pseudo-second-order model. The adsorption balance capacity was obtained as 50.8mgg~(-1) (298K), and the adsorption balance capacity decreased with increasing of temperature, which showed that the adsorption process was exothermic. The adsorption activation energy (Ea) was calculated as 5.76kJ-mol~(-1), and it showed that the adsorption process was Physical adsorption. This study explored new treatment channels for lignite comprehensive utilization..
机译:通过褐煤提供褐煤活性炭,该褐煤特别处理。研究了褐煤活性炭煤气化废水的吸附能力和机制。通过剩余溶液中的COD浓度获得不同时间的褐煤活性炭的吸附容量。采用三种简化的动力学模型:采用伪一阶,伪二阶,脊髓柱扩散方程来检查吸附过程的机制。结果表明,吸附可以由伪二阶模型表示。获得吸附平衡能力为50.8mgg〜(-1)(298K),随着温度的增加而降低吸附平衡能力,表明吸附过程是放热的。吸附活化能量(EA)计算为5.76kJ-mol〜(-1),并显示吸附过程是物理吸附。本研究探索了褐煤综合利用的新治疗渠道。

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