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Investigation of Surface Activation Bonding for Elucidation of Deposition Mechanism of Cold Spraying

机译:冷喷涂沉积机理阐明表面活化键的研究

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In order to investigate particle bonding mechanisms of Cold Spray (CS) technique, one of bonding technique, which has similar to the CS bonding mechanism, Surface Activation Bonding (SAB) technique was studied. The SAB activates solid surfaces by removing the oxide layer by using a fast atom beam (FAB), and then joins activated surfaces. In this study, more than 20 combinations of Al, Fe (3N and 4N), SUS304, Zn, Ni and Cu were used for bonding experiments at room temperature. The bonding interfaces were carefully observed by SEM. Al, which can make oxides easily, tended to be hard to bond compared with the other metals. It is thought that Al surfaces can oxidize during FAB treatment. On the other hand, Ni, Zn and Cu, which has low free energy of oxides formation, seemed to be easy to bond. Even if, it is combination with Al, Zn and Cu bond easily. Therefore, the free energy of oxides formation (-ΔG_(300)) and self-diffusion coefficients (D_(300)) are important parameters of bonding for metallic materials at room temperature.
机译:为了研究冷喷雾(CS)技术的颗粒键合机制,研究了与CS键合机理相似的粘接技术之一,表面活化粘合(SAB)技术。通过使用快速原子束(Fab)除去氧化物层,然后通过快速去除氧化物层,然后连接活性表面。在该研究中,使用Al,Fe(3N和4N),SUS304,Zn,Ni和Cu的20多种组合用于在室温下粘合实验。通过SEM仔细观察键合界面。 Al,可以容易地使氧化物能够与其他金属相比难以粘合。据认为,Al表面可以在Fab处理期间氧化。另一方面,氧化物形成具有低自由能量的Ni,Zn和Cu似乎易于粘合。即使,它也容易与Al,Zn和Cu键组合。因此,氧化物形成的自由能(-ΔG_(300))和自扩散系数(D_(300))是室温下金属材料键合的重要参数。

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