Effect of butane diacid on crystal morphology and reaction process of a-calcium sulfate hemihydrate in preparation from flue gas desulphurization gypsum

摘要

Modifying crystal morphology was the key technology of the preparation of a-calcium sulfate hemihydrate from flue gas desulphurization gypsum using the hydrothermal method under atmospheric pressure. For exploring the mechanism of butane diacid effect on crystal morphology of a-calcium sulfate hemihydrate in preparation from flue gas desulphurization gypsum, the crystal morphology, convert ratio, and reaction process of a-calcium sulfate hemihydrate were studied by scanning electron microscope observation, and crystal water testing. The results showed, firstly, crystal modifier made the growth rates of crystal in all directions equal and made the crystal into hexagonal short column, by selectivity adsorbing on (111) crystal plane of a-calcium sulfate hemihydrate to form buffer film layer which hindered combining and growing of crystallization unit on the crystal plane of c-axis direction. Secondly, butane diacid was a good crystal modifier. When adding butane diacid of optimal amount of 0.02%~0.05%, the crystal morphology of a-calcium sulfate hemihydrate was satisfactory, the crystal length-diameter ratio was 1:1, but the convert ratio was only 91%~93%.