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The Structure and Properties Research on Poly (lactide-co-trimethylene carbonate) Film Prepared by Blow Molding

机译:吹塑制备的聚(丙交酯 - 共聚碳酸亚甲酯)膜的结构与性能研究

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The poly (lactide-co-trimethylene carbonate) copolymers are prepared by ring opening polymerization and catalyzed by SnOct and their films are prepared by blow molding. The ~1HNMR study demonstrates that PLA-PTMC copolymers were successfully obtained and the graft way is A-B model. The water vapor permeability (WVP) of the films decreases with the increasing TMC content due to the formation of denser structure. The mechanical measurement reveals that the tensile strength of blown films has been declined with the increasing TMC content, but the elongation at break is improved and the tensile strength can be satisfied for the requirement of film product. Therefore, the copolymer film will be great prospect in the application of food and beverage packing.
机译:聚(丙交酯 - 共聚碳酸亚甲基酯)共聚物通过开环聚合制备,并通过SnOCT催化,并且它们的薄膜通过吹塑制备。 〜1HNMR研究表明,成功获得了PLA-PTMC共聚物,移植方式是A-B型。由于浓度结构的形成,薄膜的水蒸气渗透率(WVP)随着TMC含量的增加而降低。机械测量表明,随着TMC含量的增加,吹膜的拉伸强度已被下降,但是改善了断裂的伸长率,并且可以对薄膜产品的要求满足拉伸强度。因此,共聚物薄膜在应用食品和饮料包装中是巨大的前景。

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