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Electrochemical and Structural Changes in Cerium Based Conversion Coatings During Exposure to Salt Spray

机译:盐喷雾期间铈基转化涂层电化学和结构变化

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Cerium-based conversion coatings on aluminum alloy 2024-T3 substrates were characterized after various exposure times in salt spray corrosion testing. Coatings post-treated in phosphate solutions exhibited no visible corrosion after seven days. Impedances doubled for these coatings after 12 hours of testing and a ~150 nm thick alumina layer developed after 24 hours of exposure, leading to the conclusion that post-treated coatings facilitated the formation of a protective alumina layer. As-deposited coatings exhibited significant corrosion after 24 hours of exposure and had impedances that were an order of magnitude lower than post-treated coatings. Subsurface voids present underneath coatings corroded into nodules of alumina on the surface of as-deposited coatings. In contrast, the voids corroded into small pits with little corrosion product present in post-treated coatings, which was attributed to a protective oxide present around the voids.
机译:在盐喷涂腐蚀试验中的各种曝光时间后,在铝合金2024-T3基板上的基于铈的转化涂层。磷酸盐溶液后处理的涂料在七天后没有显示出可见的腐蚀。在测试12小时后,阻抗增加了这些涂层,并且在暴露24小时后产生〜150nm厚的氧化铝层,导致后处理后的涂层促进了保护性氧化铝层的形成。沉积涂层在暴露24小时后表现出显着的腐蚀性,并且具有比后处理后涂层低的数量级的阻抗。存在涂层下方的地下空隙被腐蚀成氧化铝的结节在沉积的涂层表面上。相反,空隙腐蚀成小凹坑,其后处理过的涂层中存在较少的腐蚀产物,其归因于存在于空隙周围的保护氧化物。

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