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Predictive Tool for Estimation of Potential Precipitation From an Equilibrated Calcium Carbonate Aqueous Phase

机译:从平衡碳酸钙水相估计潜在沉淀的预测工具

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CO 2 sequestration in saline aquifers has been proposed as one of the most practical options for reducing CO 2 emissions into the atmosphere. Massive CO 2 injection into an aquifer would alter the geochemical equilibrium between the rock-forming minerals and the formation water. In this work, a novel and simple predictive tool is presented to estimate the formation of calcium carbonate scaling as a function of pH, temperature, ionic strength of the solution, calcium cation concentration, bicarbonate anion concentration and carbon dioxide mole fraction when the water mixture is saturated with a gas containing CO 2 , to evaluate the effect of solution conditions on the tendency and extent of the precipitation. The proposed simple method covers concentration for calcium cation concentration, or bicarbonate anion concentrations up to 10000 mg/L, temperatures up to 90°C, total ionic strength up to 3.6 and pH values ranging between 5.5 and 8. The predicted values are found to be in good agreement with the reported data with average absolute deviations being less than 2.6%. The proposed tool is superior owing to its accuracy and clear numerical background based on Vandermonde matrix, wherein the relevant coefficients can be retuned quickly for various cases. Key words: Calcium carbonate, Scale, Saturation index, CO2 Sequestration, Carbon dioxide, Global warming
机译:盐水含水层中的CO 2被提出作为将CO 2排放到大气中的最实用的选择之一。将大规模的CO 2注入含水层将改变岩石形成矿物和地层水之间的地球化学平衡。在这项工作中,提出了一种新颖且简单的预测工具,以估计溶液,温度,离子强度,溶液,钙阳离子浓度,碳酸氢盐阴离子浓度和当水混合物时二氧化碳摩尔分数的函数的形成用含有CO 2的气体饱和,以评估溶液条件对沉淀趋势和程度的影响。所提出的简单方法涵盖钙阳离子浓度的浓度,或碳酸氢盐阴离子浓度高达10000mg / L,温度高达90℃,总离子强度高达3.6和pH值之间的5.5和8之间的pH值。发现预测值与报告的数据同意,平均绝对偏差小于2.6%。由于其基于Vandermonde矩阵的准确性和清晰的数值背景,所提出的工具优异,其中可以快速重新调整相关系数以用于各种情况。关键词:碳酸钙,规模,饱和指数,CO2封存,二氧化碳,全球变暖

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