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Stimulation of Carbonate Reservoirs Using GLDA (Chelating Agent) Solutions

机译:使用GLDA(螯合剂)溶液刺激碳酸盐储层

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The objective of matrix acidizing process is to create channels through the damaged zone in the near wellbore. Creating channels through the damaged zone yields a negative skin and improves the recovery in oil and gas reservoirs. The use of conventional matrix acidizing treatments with HCl is not effective in some cases due to corrosion and rapid acid spending at high temperatures. Previous studies have demonstrated the use of ethylenediaminetetraacetic acid (EDTA), hydroxy ethylethylenediaminetetraacetic acid (HEDTA), and DTPA (diethylenetriaminepentaacetic acid) as alternatives for HCl to stimulate carbonate reservoirs. These chelating agents were tested only on short cores (less than 5 in. length). GLDA (L-glutamic acid-N,N-diacetic acid) chelating agent was introduced that can be used as an effective stimulation fluid for carbonate reservoirs. Unlike HCl, GLDA can be used at very low injection rates and can create wormholes without face dissolution problems or washout. Calcium carbonate cores 1.5 in. diameter of 6 and 20 in. lengths were used in this study. The optimum conditions for the formation of wormholes were studied using core flood experiments. These conditions were: flow rate, temperature, concentration and pH. Other factors such as rock permeability and core length were also examined.
机译:基质酸化过程的目的是通过靠近井筒的受损区域产生通道。通过受损区域创建通道产生负皮肤,并提高油气藏的回收。由于在高温下支出的腐蚀和快速酸支出,在某些情况下,使用常规基质酸化处理在一些情况下无效。以前的研究表明,使用乙二胺四乙酸(EDTA),羟基乙基乙基乙基二乙酰乙酸(HEDTA)和DTPA(二亚乙基三胺酸酯)作为HCl刺激碳酸盐储层的替代品。这些螯合剂仅在短芯上进行测试(少于5英寸)。引入GLDA(L-谷氨酸-N,N-二醋酸)螯合剂,其可用作碳酸盐储层的有效刺激流体。与HCl不同,GLDA可以在非常低的注射率下使用,并且可以在没有面部溶出问题或冲洗的情况下产生虫洞。碳酸钙芯1.5英寸。直径为6和20。在本研究中使用了长度。使用核洪水实验研究了形成虫洞的最佳条件。这些条件是:流速,温度,浓度和pH值。还检查了其他因素,如岩石渗透率和核心长度。

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