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Iron Oxide-based Magnetic Nanoparticles for High Temperature Span Magnetocaloric Applications

机译:用于高温跨度磁热应用的氧化铁基磁性纳米粒子

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The magnetocaloric effect of chemically synthesized Mn_(0.3)Zn_(0.7)Fe_2O_4 superparamagnetic nanoparticles with average crystallite size of 11 nm is reported. The magnitude of the magnetic entropy change (ΔS_M), calculated from magnetization isotherms in the temperature range of 30 K to 400 K, increases from - 0.16 J-kg~(-1)K~(-1) for a field of 1 T to -0.88 J-kg~(-1)K~(-1) for 5 T at room temperature. Our results indicate that ΔS_M values are much higher than primarily reported values for this class of nanoparticles. ΔS_M is not limited to the ferromagnetic-paramagnetic transition temperature; instead, it occurs over a broad range of temperatures, resulting in high relative cooling power.
机译:报道了化学合成的Mn_(0.3)Zn_(0.7)Fe_2O_4具有平均微晶尺寸为11nm的磁热磁性效应。从30k至400k的温度范围内从磁化等温线计算的磁熵变化(ΔS_m)的大小从 - 0.16J-kg〜(-1)k〜(-1)为1 t的磁场增加在室温下为-0.88J-kg〜(-1)k〜(-1)5t。我们的结果表明ΔS_M值远高于这类纳米颗粒的主要报道值。 ΔS_M不限于铁磁性顺磁化转变温度;相反,它发生在广泛的温度范围内,导致高相对冷却功率。

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