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STRESS CORROSION FRACTURE OF SILICATE GLASSES: HOW FAR CAN WATER PENETRATE

机译:硅酸盐玻璃的应力腐蚀骨折:水可以渗透到多远

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Although glass can be considered as homogeneous at scales as small as a few tens of nanometers, since it exhibits no density fluctuations beyond, its amorphous structure makes it a disordered material with respect to fracture properties. Fluctuations of the binding energies and of the orientations of Si-O bonds with respect to the external stress make it unlikely that bonds closest to the crack tip break first, despite the high stress concentration. As a consequence, glass behaves in a quasi-brittle manner rather than in a purely elastic way, although it is of course deprived of intrinsic plasticity beyond one nanometer [1].
机译:虽然玻璃可以被认为是小于几十纳米的鳞片的均匀,但由于它没有超过密度波动,其无定形结构使其成为裂缝性能的无序材料。结合能量和Si-O键相对于外部应力的波动使得它不太可能首先最接近裂纹尖端的粘合剂,尽管应力浓度高。结果,玻璃以准脆性的方式行为,而不是以纯粹的弹性方式行事,尽管当然当然剥夺了一个纳米的内在可塑性[1]。

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