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Sol-gel and PLD preparation of the lanthanum gallate-based mixed ionic-electronic conducting oxides

机译:溶胶和PLD制备镧基酯基混合离子电导氧化物

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Ionic and mixed conducting oxides (La_(0.9)Sr_(0.1))[(Ga_(1-x)Fe_x)_(0.8)Mg_(0.2)]O_(3-y) (I) and (Sr_(1.8)La_(0.2))(GaFe)O_(5.1) (II) with the perovskite and brownmillerite structures, respectively, have been prepared in forms of dense bulk ceramics and ceramic coatings by the sol-gel method. Thin films II have been grown by the pulsed laser deposition method on single crystal MgO (100) and Si (100), fused silica, and stainless steel substrates. The films grown under optimal process conditions were single-phase and homogeneous, with a high degree of preferential orientation. The structure and microstructure of the ceramic coatings have been studied by X-ray diffraction and scanning electron microscopy.
机译:离子和混合传导氧化物(LA_(0.9)Sr_(0.1))[(Ga_(1-x)Fe_x)_(0.8)Mg_(0.2)] O_(3-Y)(I)和(SR_(1.8)LA_ (0.2))(Gafe)(Gafe)O_(5.1)(II)分别通过溶胶 - 凝胶法以致密的散装陶瓷和陶瓷涂层形式制备的钙钛矿和棕色镁层结构。通过单晶MgO(100)和Si(100),熔融二氧化硅和不锈钢基板上的脉冲激光沉积方法已经生长薄膜II。在最佳过程条件下生长的薄膜是单相和均匀的,具有高的优先取向。通过X射线衍射和扫描电子显微镜研究了陶瓷涂层的结构和微观结构。

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