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RESISTIVITY CHANGE OF CATHODE GRAPHITE DURING AND AFTER ELECTROLYSIS IN ALUMINA MOLTEN SALT

机译:氧化铝熔盐电解期间和后阴极石墨的电阻率变化

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Resistivity change of cathode graphite during and after electrolysis in alumina molten salt was determined at different temperatures between 870°C and 980°C. Resistivity of cathode graphite decreased remarkably in the initial stage of electrolysis and then became almost constant for further electrolysis. On the other hand, resistivity increased with time by interrupting electrolysis. Just after the interruption, resistivity increased rapidly with time, followed by a characteristic plateau, and again increased towards a final steady value. Repeating of this cycle resulted in remarkable enlargement of resistivity. It should be noted that a large increasing ratio of resistivity of cathode graphite before and after electrolysis was observed at relatively low temperature such as 870°C. This observation suggested intercalated sodium is stabilized at lower temperature and the amount of sodium uptake increased during electrolysis. Correspondingly, the electrolysis at lower temperature provides an effective way for evaluation on degradation of cathode graphite.
机译:在870℃至980℃的不同温度下测定氧化铝熔盐期间和后阴极石墨的电阻率变化。电解初始阶段阴极石墨的电阻率显着降低,然后进一步电解几乎恒定。另一方面,通过中断电解电阻率随着时间的推移而增加。刚刚在中断后,电阻率随着时间的推移而迅速增加,其次是特征高原,再次朝向最终稳定值增加。重复该循环导致电阻率的显着放大。应当注意,在相对低的温度(例如870℃)的相对低温下观察到电解前后阴极石墨的电阻率的大量增加。该观察结果表明嵌入钠在较低温度下稳定,电解过程中钠吸收量增加。相应地,较低温度的电解提供了对阴极石墨劣化评估的有效方法。

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