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Preparation of spherical nanoporous carbons by K2CO3 activation of biomass acid liquors derived chars

机译:k2Co3衍生液体衍生液的k2Co3活化的球形纳米多孔碳的制备

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The search for new methodologies to obtain valuable nanoporous carbons from biomass residues is a hot research topic in material science. Several approaches have been assayed as it is the case of hydrothermal treatment of carbohydrates which allows the preparation of microspherical carbons with an incipient pore structure. To further develop the porosity and retain the spherical morphology, the choice of the activating agent is crucial and in recent studies we proved the potentialities of K2CO3 to obtain spherical activated carbons with tailored microporosity from a sucrose-derived biochar . The use of lignocellulosic biomass residues as source for carbohydrate units is however a more sustainable synthetic route and literature studies prove that activated carbon materials can been prepared from acid digestion of biomass followed by KOH-activation.
机译:寻找新方法,以获得生物质残留物的宝贵纳米多孔碳是物质科学的热门研究课题。 已经测定了几种方法,因为它是碳水化合物水热处理的情况,其允许使用初始孔结构制备微球碳。 为了进一步发展孔隙率并保留球形形态,可选择活化剂的选择是至关重要的,并且在最近的研究中,我们证明了K2CO3的潜在性,以获得具有来自蔗糖衍生的生物炭的量身定制微孔隙的球形活性炭。 然而,使用木质纤维素生物质残留物作为碳水化合物单元的来源是更可持续的合成途径和文献研究证明了活性炭材料可以由生物量的酸消解,然后是KOH活化制备。

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