Application of Microcalorimetry to the Study of Interactions in Coating Formulations

摘要

Water based coating formulations contain manycomponents, such as latex binder, pigment, dispersant, thickener, and surfactant. Complex interactions between these components affect properties of the coating in both the wet and dried states. For example, rheologyof the paint is dependent on the interactions of components in the formulation. Pigment interaction can affect the degree of dispersion and, therefore, have ramifications on end use properties such as hiding and tint strength of the paint film. Isothermal Titration Calorimetryhas been used to determine the enthalpyof interaction of the coating components. Representative examples will be given to demonstrate structure-propertyrelationships that correlate the interactions of latex, pigment, surfactant, dispersant, and thickener with paint viscosityas well as end use performance parameters such as adhesion and tint strength.