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Supercritical Extraction as an Alternative Route for Upgrading the Petroleum Atmospheric Residuum(Abstract)

机译:超临界提取作为升级石油大气静置的替代途径(摘要)

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摘要

The present scenario of the global oil production is characterized by the new discoveries and exploration of ultra-heavy and bituminous crude oils. In this scenario, is of great importance, the development of technology for processing the residuum of atmospheric distillation able to withdraw a greater range of products with high added value generating less waste and ensuring that this waste has an appropriate destination. The supercritical extraction represents a promising alternative concerning high product quality and recovery. Moreover this technique is considered a clean technology due to the possibility of the minimization of energy consumption in the solvent recovering that is recycled to the process. The residue of atmospheric distillation that is a cut of high molecular weight and low added value, but still contains fractions of commercial interest in conventional route, is sent to the vacuum distillation followed by the propane desasphaltation via liquid-liquid extraction. The present work proposes an alternative route and uses a processes simulator to evaluate the supercritical extracting process of the atmospheric distillation residue investigating the use of carbon dioxide, propane and the mixture of carbon dioxide and propane as the solvents for the extraction.
机译:全球石油产量的现行情景的特点是新发现和勘探对超重和沥青原油。在这种情况下,具有重要的是,用于处理大气蒸馏的残留的技术的开发能够撤回更多的产品,具有高附加值产生较少的废物,确保该废物具有适当的目的地。超临界萃取代表了有关高产品质量和恢复的有前途的替代方案。此外,该技术被认为是一种清洁技术,因为可以最小化能量消耗的溶剂回收到该方法的溶剂恢复。大气蒸馏的残余物,其是高分子量和低附加值的切口,但仍然含有常规途径的商业兴趣的级分,被送到真空蒸馏,然后通过液 - 液萃取脱沥青。本工作提出了一种替代路线,并使用流程模拟器来评价大气蒸馏残余物的超临界提取过程,研究使用二氧化碳,丙烷和二氧化碳混合物和丙烷作为萃取的溶剂。

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