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Comparison between Extensional Rheological Properties of Low Density Polyethylene Melt in SER and RME Rheometric Systems

机译:梭中低密度聚乙烯熔体延伸流变性能与RME流变系统中的延伸流变性能

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Precise evaluation and notional prediction of extensional rheological behaviour of polymeric melts and solutions are of significant importance in polymer industry. This is evident in the well documentation of the dominance of elongational deformation of polymeric systems in processes such as melt spinning, blow moulding, biaxial stretching of extruded sheets, etc. The relevant commercial extensional rheometers thus far discussed in the literature are RME and SER. This research, for the first time, compares the extensional viscosity measurements of low density polyethylene at 140, 150, and 170°C through RME and SER devices. Despite the observed similarities found in this comparative investigation, the main difference was laid in maximum Hencky strain, strain hardening viscosity, and the variation of those rheological properties with testing temperature of the samples.
机译:聚合物熔体和溶液的延伸流变行为的精确评价和局部预测在聚合物工业中具有重要意义。这在诸如熔融纺丝,吹塑,挤出片的熔体纺丝,吹塑,双轴拉伸等过程中的聚合物系统的伸长变形的优势的良好变形的良好变形的优势中是明显的。迄今为止在文献中讨论的相关商业延伸流变仪是RME和Ser。这项研究首次将低密度聚乙烯的延伸粘度测量在140,150和170℃至RME和SER器件中比较。尽管在该比较调查中发现了观察到的相似之处,但主要差异是最大的Hencky菌株,应变硬化粘度以及样品测试温度的流变性质的变化。

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