In this study a group of resorcinol-formaldehyde carbon cryogels (CC) have been processed chemically, via catalysis and activation, to obtain varied nanostructures and pore size distributions. To understand the relation between structure and electrochemical properties the capacitor can be studied as a dielectric system composed of a porous electrode and the electrolyte (Tetraethylammonium tetrafluoroborate in propylene carbonate). Using Electrochemical impedance spectroscopy (EIS) the complex capacitance and power are used to study the behavior of the system below the relaxation frequency f_o (Φ = -45°). Therefore, the relaxation of the capacitor system at the low frequency range, f展开▼