Thermodynamic Research of The Dissolving of Chrysocolla (CuSiO_3·H_2O) in The Ammonia-Ammonium Chloride-Water System

摘要

In order to make clear the dissolving characteristic of the chrysocolla (CuSiO_3·H_2O) in the ammonia-ammonium chloride solution, a thermodynamic model of the chrysocolla (CuSiO_3·H_2O)-ammonia-ammonium chloride-water system is established using the exponential computation method based on both mass balance and charge balance equations. The equation group of the thermodynamic model is solved by the MATLAB Soft on PC. The condition which is favorable for dissolving high concentration of copper in solution is making out. The stable area of chrysocolla (CuSiO_3·H_2O) and the condition of chrysocolla (CuSiO_3·H_2O) converting to atacamite (Cu(OH)_(1.5)Cl_(0.5)) is also studied. A group of experiments are designed to validate the veracity of the results of the thermodynamic calculation.