CHARACTERIZATION OF ZINC CONTAINING RESIDUES FROM METALLURGICAL PROCESSES

摘要

The recovery of valuable metals from residues like dusts and sludges is nowadays state of the art. Depending on the complex constitution, a recovery of different metals can - in the majority of cases - only be performed with considerable energy input in high temperature processes together with insufficient yields and newly generated residues. Often, the behavior of the dust or sludge in the process during melting or reduction is unknown. In this work, a detailed characterization of selected residues like steel mill filter dusts, cupola furnace dusts and leaching residues is done. The different steps of getting from solid particles into a homogenous liquid phase were investigated. Although high temperature processing leads to high reaction speeds, the complexity of residues keeps the system away from thermodynamic equilibrium. With this research program, some basics are generated to understand smelting and reduction and the gap between thermodynamical calculations and real behavior can be explained.