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KINETICS OF KEROGEN EXTRACTED FROM GREEN RIVER OIL SHALE MEASURED AT DIFFERENT PRESSURES

机译:在不同压力下测量的绿河油页岩中提取了Kerogen的动力学

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摘要

Recently there has been renewed interest in the possibility of obtaining liquid hydrocarbon fuel from shale oil deposits. The Green River formation of oil shale has been extensively studied due to the potential of this resource, but many of these studies were conducted over 20 years ago and the studies mainly dealt with atmospheric retorting conditions. A recent approach to shale oil production is through in-situ processes. These processes will obviously operate with overburden pressures that are greater than atmospheric retorting conditions. The present research explores the kinetic parameters for the extracted kerogen using TGA methods. These methods allow the fitting of data using non-linear regression techniques to determine the activation energies and pre-exponential factors for the pyrolysis of the kerogen in an inert atmosphere.
机译:最近,对从页岩油沉积物获得液态烃燃料的可能性已经重新进行了兴趣。由于这种资源的潜力,已经广泛研究了石油页岩的绿色河流,但这些研究中的许多研究是在20年前进行的,并且研​​究主要处理大气脱果条件。最近的页岩油生产方法是通过原位进程。这些过程明显地使用覆盖压力,这些压力大于大气脱果条件。本研究探讨了使用TGA方法探讨了提取的角膜原的动力学参数。这些方法允许使用非线性回归技术的数据拟合,以确定惰性气氛中Kerogen热解的激活能量和预指数因素。

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