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Carbon Aerogels -Supported Pt with Applications in Fuel-Cells

机译:碳气凝胶与燃料电池应用的应用

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Highly dispersed platinum (Pt)-based nanoparticles still remain the most practical catalysts in fuel cells technology [1]. These Pt nanoparticles are normally supported on carbon particles in order to increase the active Pt surface and improve the catalyst utilization [2]. The researches in field are oriented to improve the support materials with nanometer Pt aiming at low densities, high surface area, continuous porosity and high catalytic activity, lower poisoning [3-5]. The main focus of this paper is the development of carbon aerogel-supported Pt as better alternative catalyst to Pt/C. The carbon aerogel-supported Pt catalysts were prepared by a conventional borohydride reduction method. The electrochemical characteristics and the catalytic activity for oxygen reduction of the carbon aerogel-supported Pt based catalysts were evaluated and compared with Pt/C. In addition EDAX measurements were done to evaluate the final content of metal catalyst related to the carbon content. The results conclude that carbon aerogels are promising low Pt loading support keeping the catalyst activity at high level.
机译:基于高度分散的铂(Pt)纳米颗粒仍然是燃料电池技术中最实用的催化剂[1]。这些PT纳米颗粒通常在碳颗粒上负载,以增加活性Pt表面并改善催化剂利用[2]。田间的研究旨在改善纳米PT的支撑材料,旨在低密度,高表面积,连续孔隙率和高催化活性,低中毒[3-5]。本文的主要重点是将碳气体支持的PT的开发为Pt / C的更好的替代催化剂。通过常规的硼氢化物还原方法制备碳气体负载的Pt催化剂。评估电化学特性和氧气减少碳吸附的PT基催化剂的催化活性,并与Pt / C进行比较。此外,进行EDAX测量以评估与碳含量有关的金属催化剂的最终含量。结果得出结论,碳通风凝胶具有低于Pt加载载体,使催化剂活性在高水平保持较低。

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