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Synthesis of zeolites using N,N'-tetramethylen-bis-(N-methylpiperidinium)dihydroxydes as directing agent

机译:使用N,N'-四甲基 - 双 - (N-甲基哌啶)二羟基作为引导剂的合成沸石

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The synthesis of two new materials referred to as ERS-13 and ERS-14 has been obtained using N,N'-tetramethylen-bis-(N-methylpiperidinium)dihydroxydes(M4BP(OH)2)as structure directing agent.The new phases were characterized by X-Ray Diffraction and Transmission Electron Microscopy.ERS-13 is most likely a layered material with a structure close to the previously reported ITQ-8.ERS-14 is a disordered zeolite material,and,similarly to zeolite ITQ-10 and ITQ-16,belongs to the family of zeolite beta.However,ERS-14 shows a weak XRD peak at 3.8° of 29(1=1.54178 A)never reported,testifying a periodicity of 23.6A.
机译:使用N,N'-四甲基二甲基 - 双(N-甲基哌啶)二羟基(M4BP(OH)2)作为结构指导剂,得到了两种称为ERS-13和ERS-14的新材料的合成。新阶段通过X射线衍射和透射电子显微镜表征。-13最可能是具有接近先前报告的ITQ-80的结构的层状材料是无序的沸石材料,并且类似于沸石ITQ-10和ITQ-16属于沸石β的家族。然而,ERS-14显示出39°(1 = 1.54178A)的3.8°的弱XRD峰,从未报道,验证了23.6A的周期性。

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