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Method for Characterizing the Aggregation of Wax Crystals and Improvingthe Wax Deposition Model

机译:表征蜡晶体聚集并改善蜡沉积模型的方法

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Wax crystals can aggregate and precipitate when the oil temperature decreases to below the wax appearancetemperature(WAT)of waxy crude oil,which has undesirable effects on the transportation of crude oilin pipelines.Thermodynamic models considering the molecular diffusion,shearing dispersion,and shearstripping as well as hydrodynamic models have been developed for predicting the wax deposition incrude oil pipelines.However,the aggregation behavior of wax crystals during crude oil production andtransportation is not well understood.The microscopic rheological parameters have not been related tothe bulk flow parameters in the shearing field,and the prediction of the wax deposition behavior undercomplex conditions is restricted by the vector characteristics of the shearing stress and flow rate.A setof microscopic experiments was performed in this study to obtain the basic information from imagesof wax crystals in shearing fields.A novel method of fractal dimensional analysis was introduced toelucidate the aggregation behavior of wax crystals in different shear flow fields.The fractal methodologyfor characterizing wax crystal aggregation was then developed,and a blanket algorithm was introducedto compute the fractal dimension of the aggregated wax crystals.The flow characteristics of waxy crudeoil in a pipeline were correlated with the shearing stress work,and a wax deposition model focusingon shearing energy analysis was established.The results indicate that a quantitative interpretation of thewax crystal aggregation behavior can be realized using the fractal methodology.The aggregation behaviorof the wax crystals is closely related to the temperature and shearing experienced by the waxy crudeoil.The aggregation behavior will be intensified with decreasing temperature and shearing effect,anda wider fractal dimension distribution appears at lower temperatures when the same shear rate range isemployed.The lower the fractal dimensions obtained at high temperature and strong shear action,the weakerwill be the nonlinear characteristics of the wax crystal aggregation structure,and thus,the potential waxdeposition will be inhibited during waxy crude oil production and transportation.Furthermore,the improvedmodel provides a method for discussing the effects of the operating conditions on wax deposition.Theaverage relative deviation between the improved model prediction results and experimental results fromthe literature is 3.01%-5.32%.The fractal methodology developed in this study and the improvement in wax deposition modeling are beneficial for understanding and optimizing flow assurance operations in thepipeline transportation of waxy crude oils,and the results are expected to facilitate a better understandingof the wax crystallization and deposition mechanism.
机译:当油温降低到蜡状原油的蜡显影率(Wat)以下时,蜡晶体可以聚集和沉淀,这对粗油水管道的运输产生了不希望的影响。考虑分子扩散,剪切分散和沉皮的热力学模型也是如此由于已经开发了用于预测蜡沉积的流体动力学模型,但是,在原油生产和分析过程中蜡晶体的聚集行为尚不清楚。微观流变参数在剪切场中没有相关的散装流量参数,和的蜡沉积行为undercomplex条件预测由剪切应力的矢量特性的限制,SETOF微观实验在本研​​究中进行的,以获得在剪切fields.A新颖的方法从imagesof蜡晶体的基本信息流rate.A分形尺寸分析介绍D诱发蜡晶体中蜡晶体的聚集行为。然后开发了表征蜡晶聚集的分形方法,引入了橡皮蜡晶体的分形尺寸。管道中的蜡质粗糙的流动特性与剪切应力工作相关,建立了蜡沉积模型聚焦剪切能量分析。结果表明,使用分形方法可以实现瓦克斯晶体聚集行为的定量解释。蜡晶的聚集行为与之密切相关由蜡状粗糙度所经历的温度和剪切。通过降低温度和剪切效果,聚集行为将加剧,当较低的剪切速率范围放置时,较宽的分形尺寸分布出现在较低的温度下。在高温下获得的分形尺寸较低争吵NG剪切作用,弱势件是蜡晶体聚集结构的非线性特征,因此,在蜡质原油生产和运输过程中将受到抑制潜在的蜡沉积。繁殖的方法,改良模型提供了讨论操作条件的影响的方法蜡沉积。改进的模型预测结果与文献的实验结果之间的相对偏差为3.01%-5.32%。本研究中开发的分形方法和蜡沉积建模的改善是有益于理解和优化在普遍运输中的流量保证行动蜡质原油,预计结果有助于更好地理解蜡结晶和沉积机制。

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